Abstract
In the past few years there has been growing interest in memristive devices. These devices rely on thin metal oxide films with a peculiar structure and composition, making precise control of oxide features vital. To this end, anodic oxidation allows a very large range of oxides to be formed on the surface of valve metals, whose thickness, structure and functional properties depend on the process parameters introduced. This work reports how memristive anodic oxides were obtained on titanium and other valve metals, such as niobium and tantalum.
Anodic oxidation was performed on valve metals by immersion in H2SO4 or H3PO4 electrolytes and application of voltages ranging from 10 to 90 V. The memristive behavior was evaluated by cyclic voltammetry.
The behavior of differently grown oxides was compared to identify the best conditions to achieve good memristive performances. High voltages were identified as not suitable due to the excessive oxide thickness, while below 20 V the film was not thick and uniform enough to give a good response. Surface preparation also played a major role in the observation of memristive properties.
Optimal surface preparation and anodizing conditions were seen to give high memristive perfomances on both titanium and niobium oxides, while on tantalum oxides no reproducibility was achieved.
J Appl Biomater Funct Mater 2016; 14(3): e290 - e295
Article Type: ORIGINAL RESEARCH ARTICLE
DOI:10.5301/jabfm.5000290
Authors
Maria Vittoria Diamanti, Riccardo Pisoni, Andrea Cologni, Andrea Brenna, Fernando Corinto, MariaPia PedeferriArticle History
- • Accepted on 17/03/2016
- • Available online on 30/05/2016
- • Published online on 26/07/2016
Disclosures
This article is available as full text PDF.
Introduction
Information storage devices are dominated by silicon technology and nanotechnologies, which have led to circuital elements being shrunk to below 100 nm. Si-based flash memories represent the most diffuse nonvolatile memory (NVM) systems, owing to high data density and low fabrication costs. Still, they suffer from low endurance, low write speed, and high voltages required for write operations; moreover, downscaling is now reaching physical limits, as features size cannot keep shrinking at the current speed, posing a limit to memory density.
To overcome current NVM problems, several alternative memory concepts are being explored. Among these, NVMs based on resistance (switching) random access memory (RRAM) have attracted the most attention (1-2-3). The work presented here deals with a particularly interesting class of RRAM in which redox reactions and nano-ionic transport processes play the key role: memristive devices. Memristors were first theorized in 1971 (4), but only in 2008 was a memristive characteristic actually observed in a metal/oxide/metal device built with Pt and TiO2 (5). The memristive behavior of TiO2 is based on the presence of oxygen vacancies moving forward and backward across the electronic barrier at the metal/oxide interface, generally through the formation of an oxygen vacancy filament, which results in changes to oxide resistance (6-7-8-9). The existence of such a filament has already been proved both experimentally by applying microscopy-based techniques, and through modeling (10-11-12-13-14).
This research study presents the technique of anodic oxidation as a means to produce metal oxides with added functionalities, specifically a memristive behavior, with a special focus on titanium, niobium and tantalum oxides (15). This technique can lead to the controlled production of oxide films on valve metals, and to the tuning of growth kinetics and oxide properties as a function of process parameters. Controlling electrochemical parameters (cell voltage, electrolyte composition, anodizing time) defines the oxide thickness, morphology, chemical and structural composition (15-16-17), which in turn is responsible for titanium surface properties such as corrosion resistance, insulation or biocompatibility (18, 19). Anodizing is a cheap, room-temperature alternative to physical and chemical fabrication methods typical of the electronics industry that are currently applied to memristor production. Furthermore, anodizing has already been demonstrated as suitable for producing memristive TiO2 films (11, 20).
Materials and methods
Anodic oxidation was performed first on titanium specimens of grade 2 following ASTM classification: 30 × 20-mm samples were cut out of a 0.5-mm thick sheet. After a series of optimization tests on titanium, niobium and tantalum were also anodized under similar conditions: both Nb and Ta were purchased in 0.1-mm thick sheets from Goodfellow. Two electrolytes were considered: sulfuric acid (0.5 M) and phosphoric acid (0.5 M), with cell voltage ranging from 0 to 100 V. Particular attention was given to low voltage oxides (25 and 30 V). Before anodizing, the metal sheet was degreased with acetone. A surface preparation step also included either mechanical or chemical polishing, performed by abrasive papers down to 1200 grit, or with a mixture of HF and HNO3, 2.5% and 17.5% by weight, respectively. The specimen was then immersed in the electrolytic cell with an activated titanium net as a counter electrode, and a constant current density was applied. The anode-to-cathode potential difference increased gradually until the desired cell voltage was reached. Current density was 10 mA/cm2.
Tests were carried out at room temperature (approx. 25°C) with no cooling and no stirring: therefore, a slight heating of the electrolyte may have occurred at high voltages in sulfuric acid due to sparking phenomena (15). Given the low current density employed and large volume of electrolyte (0.5 L) this effect was considered negligible (in the order of room temperature fluctuations) since it becomes consistent only above 100 V in the presence of large current dissipations and large oxide crystallization, neither of which were observed in this case.
After anodic oxidation the reflectance spectrum of the anodized surface was measured in the visible range by means of a Konica Minolta CM-2600d portable reflectance spectrophotometer, operating in the range of 360 to 740 nm. Given the low thickness (30-200 nm range) of the oxides produced and their amorphous nature, interference of light with the oxide film grown on the metal surface caused the appearance of interference colors, whose reflectance spectra present a sinusoidal trend. Constructive and destructive interference occurring at different wavelengths creates peaks and valleys, respectively, whose position can be associated with the oxide thickness, as described in several studies (15, 16). To calculate oxide thickness from reflectance spectra, metal oxide refractive indexes are needed. The following values of refractive index at 550 nm were chosen: nTi = 2.2, nNb = 2.3, nTa = 2.1 (21-22-23-24-25-26).
Once the oxide thickness was characterized, cyclic voltammetry was used to signal the possible achievement of a memristor. To meet this aim, the current-voltage response of the material was recorded under a cyclic voltage scan. The anodized titanium sheet was used as a working electrode by connecting the back of the titanium sample to the positive pole of the power supply, while a vertical rod with a 2-mm diameter copper tip was employed as a counter electrode. The rod tip was put in direct contact with the oxide layer: in this way, we obtained a metal-oxide-metal contact with the configuration copper-TiO2-titanium substrate, which allowed the electric properties of the oxide layer to be investigated. The cell voltage was ramped linearly versus time from 0 to Vf (0.5 V <Vf <1 V), then the scan was inverted until the specular negative potential –Vf was reached (-1 V <−Vf <-0.5 V). Finally, the voltage was ramped back to the initial 0 V. Unless otherwise stated, the scan rate was set to 4 V/min.
Results and discussion
As observed in previous works, a linear relation between oxide thickness and applied voltage emerges.
Thickness-voltage relationship of titanium, niobium and tantalum anodized in H2SO4.
The growth of applied voltage in time, representing anodizing kinetics, is reported in
(
X-ray diffraction spectra of titanium, niobium and tantalum anodized at 100 V.
After anodizing, specimens were subjected to cyclic voltammetry analyses. Current-voltage (I-V) curves of memristors typically present a hysteretic loop, characterized by a high resistance state (low slope, Roff) which switches to low resistance (high slope, Ron) when a voltage threshold is exceeded, and vice versa when a new voltage threshold occurs (
Bipolar switching characteristics in a voltage sweeping experiment. The set operation takes place on 1 polarity of the voltage or current, and the reset operation requires the opposite polarity. (Reprinted from: Waser R, Aono M. Nanoionics-based resistive switching memories. Nature Mater. 2007; 6: 833-840 with permission from Nature Publishing Group)
At first, the different oxide thicknesses produced by increasing cell voltages was considered a fundamental parameter for defining memristive performance: memristivity is supposed to depend inversely on oxide thickness (5, 28). In fact, what was observed was an increasing trend in loop opening (i.e., Roff/Ron ratio) and symmetry with cell voltage until 30 V was reached, with a maximum loop opening at 25 V, above which the memristive response started to deteriorate (
Very thin anodic oxides did not behave as memristors, also owing to a possible island growth of the anodic oxide, which may still present conductive behavior below 10 V (approx. 40-nm thickness) due to parts of the metal surface that are still exposed to the environment. This peculiar growth behavior was observed in a previous work with conductive AFM measurements (11). Consequently, the memristive response is shielded by the high conductivity of the metal.
I-V curves obtained on oxides grown in sulfuric acid at different voltages.
I-V curves obtained on oxides grown in phosphoric acid at different voltages.
The sample anodized at 25 V was one of the best performing ones. Its Roff was evaluated to be approximately 17 Ω, while Ron was 0.5 Ω, which gives an off-on ratio higher than 30, representative of a good memristive element. As a comparison, oxides grown in H2SO4 only produced a maximum off-on ratio of 6. Yet, a poor symmetry about the origin was obtained: this deviation may be ascribed to oxide defects, which may trap the motion of oxygen vacancies through the oxide. More interestingly, after repeating tests on mechanically polished samples in order to improve surface homogeneity, oxides produced in H3PO4 exhibited a higher symmetry in the response (
I-V curve obtained on mechanically polished titanium anodized in phosphoric acid at 30 V.
Based on the results described above, it was possible to define an optimized anodizing procedure, which consisted of subjecting the metal to mechanical polishing and anodic oxidation in H3PO4 at voltages of either 25 or 30 V. The same procedure was then applied on niobium and tantalum: results are reported in
In particular, anodized niobium exhibited interesting results, with performances similar to those of anodic TiO2 combined with higher reproducibility of the experimental results.
I-V curves obtained on mechanically polished niobium and tantalum anodized in phosphoric acid at 30 V.
Although a precise switching mechanism was not identified clearly, given the influence of a wide range of oxide features tested – thickness, composition, crystalline structure – it is generally accepted that voltage stresses applied during cyclic voltammetry drive the motion of oxygen ions through the oxide. Therefore, it is possible that a low resistance will be observed when the oxide has a homogeneous TiO2-x composition, since
Conclusions
The experimental work here presented is aimed at identifying suitable anodizing conditions to achieve the formation of memristive oxides on valve metals, in particular titanium, niobium and tantalum. Oxide thickness plays a major role: neither too thin nor too thick anodic oxides need to be chosen to have a good memristive response, since the desirable oxide thickness ensuring complete surface coverage and avoiding the insulation provided by thicker layers is a few tens of nanometers. Concerning the metal substrate composition, only anodic Nb2O5 and TiO2 actually showed interesting switching properties, while several problems of reproducibility were experienced when analyzing Ta2O5.
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Authors
- Diamanti, Maria Vittoria [PubMed] [Google Scholar] 1, * Corresponding Author ([email protected])
- Pisoni, Riccardo [PubMed] [Google Scholar] 1
- Cologni, Andrea [PubMed] [Google Scholar] 1
- Brenna, Andrea [PubMed] [Google Scholar] 1
- Corinto, Fernando [PubMed] [Google Scholar] 2
- Pedeferri, MariaPia [PubMed] [Google Scholar] 1
Affiliations
-
Giulio Natta Department of Chemistry, Materials and Chemical Engineering, Politecnico di Milano, Milan - Italy -
Department of Electronics and Telecommunications, Politecnico di Torino, Turin - Italy
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